Byakuya has slate gray eyes and long black hair, which he keeps up in intricate white headpieces called kenseikan that symbolize his nobility as the head of the Kuchiki family, one on top of his head and another on the right side. He wears the standard captain uniform along with a white scarf made by the master weaver, Tsujishirō Kuroemon III. The scarf is made from the silver-white, windflower light silk (ginpaku kazahana no uzuginu) and is a family heirloom that is handed down from generation to generation and is given to each head of the Kuchiki family. The scarf alone is worth enough to buy ten mansions in the Seireitei. He also wears fingerless white tekkou that cover only the back of his hands.
A year and a half after the defeat of Aizen, Byakuya wears his kenseikan at the back of his head.. He now wears a variation of the captain haori with a high collar which has light gold on its edges and small, light gold tassels attached to the corners. The white scarf is also no longer a part of his attire.
As the 28th head of the Kuchiki clan, Byakuya acts in an aristocratic manner — he seems always serene and apathetic towards other people, even when he is actually deeply conflicted. He is also extremely calm, even in battle. He generally acts indifferent, bordering on arrogance, to most situations that he is faced with as shown from how he rarely views his opponent as being worth his time. Byakuya is easily offended if his name is not used properly. As such, he views Ichigo Kurosaki in disdain for always referring to him improperly. When Byakuya talks with Ichigo, he calls him by his full name. Byakuya is very perceptive and is fully aware of the limits of his abilities and usually anything he states in comparison to an opponent is justified. However, when he was younger, he was quick to anger and very hotheaded, as noted by his grandfather.
Byakuya strongly believes in law and order. As the head of one of the great noble families and as a Gotei 13 captain, he works hard for a peaceful society. He feels that if someone in his position does not follow the rules as a good example, then no one will follow them. He believes that to maintain the order, all law-breakers must be punished, even if that goes against his own wishes. Byakuya feels that "part of a captain's responsibilities are to make sure the lieutenant's responsibilities are taken care of". In spite of his icy and regal manner, Byakuya cares for and protects those important to him. After the events of the Aizen incident, he admitted that law isn't perfect and became more lenient towards his adoptive sister, Rukia.
Byakuya is popular among the female Shinigami of Soul Society, and was voted number one in the "captain we desire to release a photo book for" poll taken by the Shinigami Women's Association. He likes Japanese cherry blossoms, night-time walks, spicy food, and bananas, but he does not like sweets. Byakuya excels in calligraphy.
Info from : http://bleach.wikia.com/
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