Harribel has dark skin, green eyes, blonde eyelashes, and messy short blonde hair which has three braided locks. She wears a variation of the Arrancar jacket that covers the lower part of her face downward, while baring a good portion of the lower half of her large breasts. The jacket, unlike that of other Arrancar, has a zipper running along its entire length that is opened from the bottom upwards. The jacket's sleeves completely envelop her arms, terminating in black glove-like extensions at her extremities, resembling the appearance of a cat's paw. Harribel carries her Zanpakutō horizontally across her back (similar to Suì-Fēng). The sword itself is notably broad and short compared to others, completely hollow in the middle, and has a western-style guard.
The remnants of her Hollow mask consist of the sides of her face and her mouth, as well as an extensive area below and around her neck extending down to, and also covering, her nipples; she usually hides these Hollow remnants from view with her jacket. Harribel's mask fragment gives her a similar appearance to Grimmjow Jaegerjaquez, at least in regards to the teeth. To date she has the most intact mask of any Arrancar not including the incomplete Grand Fisher (though the mask is removed upon her Zanpakutō's release). Her Espada tattoo is oddly placed on the left side of her right breast. The location of her Hollow hole is in her lower abdomen where her womb would be, making it unseen.
Her appearance from the time before she became an Arrancar mostly resembled her released state, but most of her body and face was covered by white hollow-bones and her weapon was part of her arm. Her hair and eyes were, however, exposed.
In contrast to the majority of her fellow Espada, Harribel is calm, taciturn, level-headed and analytical, preferring not to engage in combat; she is content with silently observing both parties until the fighting reaches its conclusion, and refuses to fight unless she or her Fracción are challenged or ordered by her superiors (excluding Baraggan, sharing her history with him). She strongly opposes the notion of killing others, especially if done to gain power. However, when she is betrayed by Aizen, Harribel angrily attacks him, showing that, while rare, Harribel can be quite aggressive and brutal. Unlike most of her comrades, Harribel does care for her Fracción, as she is noticeably upset when she senses their presences fading and angrily assaults Hitsugaya seconds after their defeat at the hands of Captain-Commander Yamamoto.
She views Aizen and his powers in high regard, which appears to be reciprocated by Aizen to a certain extent, as he seems unconcerned with the prospect of his top three Espada fighting a numerically-superior force led by six Shinigami captains without his aid. Whenever she is present, Aizen usually greets the group with words such as "ladies and gentlemen of the Espada" or "brothers and sisters", presumably for her exclusive benefit, as she is the only female.
Harribel's gender and associated rank in the Espada occasionally draws the unwanted attention of other people; Nnoitra Gilga attempts to provoke her into attacking him with a sharply-worded comment during the Espada meeting. She also catches the eye of Captain Shunsui Kyōraku, to the point of him mentioning his (rather positive) opinion of her abilities to his opponent.
Tier Harribel form 1
Tier Harribel form 2
Harribel as a Vasto Lorde-class Hollow.
Ola Azul , Ōra Azūru;
Spanish for "Blue Wave", Japanese for "Blue Wave Gun"): A technique in which Harribel pulls her sword back as it gathers yellow spiritual energy within the hollow portion of her blade and launches it towards her opponent, in the form of an energy blade projectile. She has also demonstrated the ability to keep the energy concentrated within the hollowed out portion of the blade and unleash it in the form of a ribbon when attacking.
La Gota , Ra Gota;
Spanish for "The Drop", Japanese for "War Drop") Harribel is able to condense large amounts of water around her blade before firing it as a blast that resembles a shark tooth. She has also demonstrated the ability to fire multiple blasts in rapid succession with relative ease. The blasts strike with enough force to demolish houses.
Info from : http://bleach.wikia.com/
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