Nel is a female Arrancar that has hazel eyes and short green hair. In her child form, her eyes are incredibly wide, the canines on her lower jaw are larger than usual, and the remains of her Hollow mask make up a cartoon-like skull which sits on the top of her head. A crack runs along the left side of the mask and four teeth on the left side of the skull are broken off. She has a large scar coming down from her forehead to her nose and a crimson line that stretches horizontally across her face below her eyes. Her clothing consists of a simple green gown with a hood which covers her entire body.
Her adult form is that of a fully-formed curvacious woman with long waving green-blue hair, retaining similar features to her child form, including the scar and the crimson line that runs across her face, but her bottom canines aren't quite as pronounced. Her gown is now torn into a skirt and a top, and her skull mask differs slightly, its features appearing sharper and less cartoonish with a pair of curved horns but still missing some of its teeth. A large "3" is tattooed on her back, indicating that she was the former 3rd Espada.
Nel's appearance is in stark contrast to her vocabulary, which contains a number of bizarre phrases and words one wouldn't expect such a small child to know, such as calling her uvula a "throat penis" and referring to herself as a masochist. Ichigo Kurosaki assumes her Hollow companions are responsible for this. Nel and her companions also represent oddities among Hollows, though most Hollows are evil, Nel actually fears Shinigami, assuming they are in fact the evil ones. In spite of this, she develops an attachment to Ichigo and follows him into Las Noches. During their super sentai intro she prefers the name "Thieves: Nel-Don-Pe." She also seems to speak with a lisp in her child form, frequently pronouncing "S"s as "T"s.
As Nelliel, she is much more mature, composed, logical, sophisticated, and intelligent than her child form. She is also relatively level-headed in terms of how to fight, stating that if one's excuse for a battle is to fight out of hatred, prejudice, or simple competition, as Nnoitra does, then it is merely instinctual and animalistic, and that it makes the challenger look "childish," "unworthy," and "not much of a warrior". Though Nelliel has proven during her last few minutes as a full-fledged Espada that it is 'acceptable' when it involves vengeance, she does not view even that as a reason to fight. Unlike many of the Arrancar, Nelliel is somewhat pacifistic, and according to her Fracción, has despised engaging in combat even when she was still among the upper ranks of the Espada, unless it involves self-defense and protecting those dear to her heart. It is for this reason that Pesche and Dondochakka decided to simply be content with her child form and banished themselves from Las Noches. She refuses to finish off weaker or injured opponents, and will stop fighting them once they've been disabled or incapacitated, a trait shared with Kenpachi Zaraki.
As witnessed during her numerous fights with Nnoitra, Nelliel's shown to be relatively calm and silent when fighting, preferring to speak only when spoken to, a rather uncommon trait among most Arrancar. She is even shown to enjoy reading, usually seen reading a book after her mission or after waiting for Nnoitra to wake up after their recent battle.
Nelliel's also shown to be a loyal, respectful, and trustworthy warrior, who will diligently follow the orders of her commander, provided said commander has proven his worth.
She's also knowledgeable, analytical, easygoing, fairly compassionate (usually towards her friends), humorous in her own right, and exhibits a cheerful, energetic demeanor when off-duty. Although having grown up physically, she somehow retains her child-like affection over Ichigo, best-shown when she unexpectedly bear-hugged him after attacking Nnoitra without realizing that Ichigo was losing consciousness (although the anime's flashback of Nel's accident suggested that she was always somewhat childish outside of combat).
Cero Doble:
She retains her attack absorption ability in her original form, but now performs it with greater ease. According to Nnoitra, Nelliel's specialty is to absorb an incoming Cero and fire one of her own while returning it, thus creating a potent Cero Doble (重奏虚閃 (セロ・ドーブル), sero dōburu, Spanish for "Double Zero", Japanese for "Heavy Performance Hollow Flash"). While her child form severely limits her Arrancar powers, she is still powerful enough to absorb and redirect a Cero blast from a Privaron Espada-class Arrancar in its released form, though the effort seems to tire her immediately. In her original form, the force(s) of the Cero Doble is augmented greatly, owing to the fact that she rebounds the attack while blending it with her own Cero, drastically increasing its power, as befits the former third Espada.
Resurrección:
Its release command is "Declare" (謳え, utae; Viz: "Praise"). Nel holds her Zanpakutō up in front of her horizontally and calls out its release command. The Zanpakutō glows as a hazy smoke emanates from it. She calls out the name of her Zanpakutō and the glow intensifies into a huge burst of spiritual energy that greatly affects the surrounding vicinity. In her new form, Nel takes the form of a brownish-green ibex-like centaur complete with a black horse's tail. Her hollow masks horns become longer and more curved and also extends slightly, framing the sides of her face, particularly the cheeks. The crack on her mask also closes up, although the missing teeth remain. Her shoulders are covered by armored white spaulders that come across the shoulder blade to the neck, she has white armored elbow guards and white armored gauntlets. The parts of the arm that aren't covered by armor are covered with a black material as well as her hands. There is a white armored ring at the base of her tail. Gamuza itself transforms into a double-sided lance. She is one of the few Arrancar known to have a weapon after her release (the releases of most Arrancar de-materializes their weapons upon their true forms being unleashed). All these features grant her the overall appearance of a medieval knight or a jouster.
Resurrección Special Ability:
The only attack she has used in this form so far is Lanzador Verde. The full extent of Gamuza's abilities are still unknown.
Lanzador Verde :
(翠の射槍 (ランサドール・ヴェルデ), ransadōru verude; Spanish for "Green Lancer", Japanese for "Jade Lance"): Nel throws her lance at her opponent with extreme speed. As it travels through the air, it begins to spin and build up spiritual energy. When it reaches its target, it acts as a drill inflicting extreme piercing damage. The technique is powerful enough to push back Nnoitra as well as break his Zanpakutō that he was using to block the attack.
Info from : http://bleach.wikia.com/
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